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people Associate Professor A. James McQuillan
Spectroscopy at the solid/solution interface
 
McQuillan photo Assoc. Prof. A. James McQuillan
Location: Science II, 5c3
Tel: +64  3  479 7928
Email: jmcquillan@chemistry.otago.ac.nz

Research group and projects

Scott Dickie (PhD student)
New dispersants for titanium dioxide based paint pigments

The titanium dioxide pigment particles are coated with aluminium oxides to which ligands having functional tails will be bound, and the modified pigments tested in collaboration with Resene Paints, who have supported this project.

 

Dave Warren (PhD student)
Surface chemistry in photocatalysis and electrocatalysis

Irradiation of TiO2 with UV light induces surface redox reactions.  Proton exchange membrane fuel cells use Pt black for electrocatalysis.  Both processes are of interest to Johnson Matthey (UK) Ltd, who have provided scholarship funding to probe the surface chemistry with IR spectroscopy.

 

Jing Yang (PhD student)
The role of siderophores in bacterial adhesion to metals

Pseudomonas aeruginosa bacteria use siderophores to sequester iron but siderophores may also facilitate bacteria adhesion to metal surfaces.  This Marsden funded project in conjunction with Iain Lamont (Biochemistry) and Phil Bremer (Food Science) is on the adsorption of siderophores and bacteria to metal (oxide) surfaces.

 

Hannah Heinrich (PhD student)
Sequestration of metal ions by thermophilic bacteria

Bacteria that thrive in metal-rich environments may be able to be utilized in bioreactors to remove heavy metals from urban waste.  The chemical nature of the metal binding is being investigated in conjunction with Chris Daughney (IGNS) and Phil Bremer (Food Science) and funded by NERF/IGNS.

 

Jihua Yang (research fellow)
Surface photovoltage spectroscopy of materials

Irradiation of semiconductors with ultrabandgap light results in contact potential differences which can reveal the nature of charge carriers and of interbandgap states.  A Kelvin probe is used to measure the CPD over a relevant wavelength range.  This project is in conjunction with Keith Gordon (Chemistry) and supported by the MacDiarmid Institute.



Ravi Harikisun (research assistant)
Bioadhesion to materials

Adsorption and adhesion of water, ligands and bacteria to metal oxide and polymer particle films.  This work is part of the programme of the Bioadhesion Group.

 

So-Young Kang (visiting PhD student)
Sequestration of metal ions by bacteria

Both IR spectroscopy and zetapotential measurements will be used to investigate the uptake of metal ions by Pseudomonas aeruginosa bacteria.  Miss Kang visits from October 2004 until March 2005 from the Gwangju Institute of Science and Technology, Gwanju, Korea.


IR spectrum of Pseudomonas aeruginosa attaching to ZnSe

 

Kiri McComb (summer student)
Adsorption of antimonite species to hydrous iron oxides

Arsenate and antimonite species are often found in waters derived from gold mining and their toxicity is of environmental concern.  Arsenates are adsorbed onto iron oxyhydroxides derived from pyrite oxidation but the corresponding behaviour of antimonates species has not hitherto been investigated.  This project is jointly with Dave Craw (Geology).

 


Group members in February 2004.  L–R: Phil Bremer, Scott Dickie, Pearl Swe, Dave Warren, Hannah Heinrich, Jim McQuillan, Jing Yang

Last modified: 10 Feb 2010
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